Product ID:204399, CHROMIUM 1 REAGENT (SEE SUPPLEMENTAL DATA)
MSDS Date:11/29/2000
FSC:6810
NIIN:01-447-6498
Status Code:A
Kit Part:Y
MSDS Number: CLSGH

Emergency Phone: 303-623-5716

Info Phone: 970-669-3050/800-227-4224

Cage: 91224

Telephone: 970-669-3050/ 303-623-5716

Cage: 91224

LITHIUM HYPOBROMITE

CAS: 13824-95-8

LITHIUM HYDROXIDE, ANHYDROUS

CAS: 1310-66-3

SODIUM SULFATE

CAS: 7757-82-6

RTECS: WE1650000

Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT: CAUSES EYE BURNS. SKIN
CONTACT: CAUSES BURNS. INGESTION: TOXIC CAUSES: SEVERE BURNS MAY
CAUSE: CENTRAL NERVOUS SYSTEM EFFECTS KIDNEY DAMAGE, DIZZINESS,
NAUSEA, VOMITING, LIVER DAMAGE, COM A, DEATH. INHALATION: CAUSES:
SEVERE BURNS, SHORTNESS OF BREATH, COUGHING. TARGET ORGANS:
KIDNEYS, CENTRAL NERVOUS SYSTEM, BONE MARROW, LIVER.CHRONIC
EFFECTS: LITHIUM COMPOUNDS HAVE BEEN IMPLICATED IN DEVELOPMENT OF
APLASTIC ANEMIA. SIGNS OF LITHIUM POISONING INCLUDE DEHYDRATION,
EXTREME WEIGHT LOSS, FINE TREMORS OF HANDS, NAUSEA, VOMITING AND
DIARRHEA, CHRONIC OVEREXPOSURE MAY CAUSE CENTRAL NERVO US SYSTEM
EFFECTS KIDNEY & LIVER DAMAGE.
Explanation of Carcinogenicity:TESTS PERFORMED ON THIS PRODUCT /
COMPONENTS GAVE INSUFFICIENT EVIDENCE TO CLASSIFY FOR
CARCINOGENICITY.
Effects of Overexposure:EYE CONTACT: CAUSES EYE BURNS. SKIN CONTACT:
CAUSES BURNS. INGESTION: TOXIC CAUSES: SEVERE BURNS MAY CAUSE:
CENTRAL NERVOUS SYSTEM EFFECTS KIDNEY DAMAGE, DIZZINESS, NAUSEA,
VOMITING, LIVER DAMAGE, COM A, DEATH. INHALATION: CAUSES: SEVERE
BURNS, SHORTNESS OF BREATH, COUGHING. TARGET ORGANS: KIDNEYS,
CENTRAL NERVOUS SYSTEM, BONE MARROW, LIVER. LITHIUM COMPOUNDS HAVE
BEEN IMPLICATED IN DEVELOPMENT OF APLASTIC ANEMIA. SIGNS OF
LITHIUM POISONING INCLUDE DEHYDRATION, EXTREME WEIGHT LOSS, FINE
TREMOR OF HANDS, NAUSEA, VOMITING AND DIARRHEA, CHRONIC
OVEREXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS KIDNEY
DAMAGE LIVER DAMAGE.
Medical Cond Aggravated by Exposure:NONE REPORTED.

First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15
MINUTES. CALL PHYSICIAN. SKIN CONTACT: WASH SKIN WITH PLENTY OF
WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN
IMMEDIATELY. IN GESTION: DO NOT INDUCE VOMITNG. GIVE 1-2 GLASSES OF
WATER. CALL PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE
ARTIFICIAL RESPIRATI ON IF NECESSARY. CALL PHYSICIAN.

Autoignition Temp:Autoignition Temp Text:ND
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:CONTACT WITH METALS GIVES OFF HYDROGEN
GAS WHICH IS FLAMMABLE MAY REACT VIOLENTLY WITH: ORGANIC
MATERIALS.DURING A FIRE, CORROSIVE AND TOXIC GASES MAY BE GENERATED
BY THERMAL DECOMPOSTION.

Spill Release Procedures:STOP SPILLED MATERIAL FROM BEING RELEASED TO
THE ENVIRONMENT. COVER SPILLED SOLID MATERIAL WITH SAND OR OTHER
INERT MATERIAL. WORK IN AN APPROVED FUME HOOD. DILUTE WITH A LARGE
EXCESS OF WATER. ADJUS T TO A PH BETWEEN 6 AND 9 WITH AN ACID SUCH
AS SULFURIC OR CITRIC. FLUSH REACTED MATERIAL TO THE DRAIN WITH A
LARGE EXCESS OF WATER.

Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN. DO NOT
BREATHE DUST. WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL
INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. STORE BETWEEN
10 AND 25 DEGREES C. KEEP AWAY FROM:ACIDS PROTECT FROM: HEAT
MOISTURE.
Other Precautions:AVOID CONTACT WITH EYES, SKIN. DO NOT BREATHE DUST.
WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:LABORATORY FUME HOOD.
Ventilation:USE GENERAL VENTILATION TO MINIMIZE EXPOSURE TO MIST, VAPOR
OR DUST.
Protective Gloves:DISPOSAL LATEX
Eye Protection:SAFETY GLASSES WITH TOP AND SIDE SHIELDS
Other Protective Equipment:HAVE A SAFETY SHOWER NEARBY.HAVE AN EYEWASH
STATION NEARBY. USE A FUME HOOD TO AVOID EXPOSURE TO DUST, MIST OR
VAPOR. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING
THIS PRODUCT. LAB COAT.
Work Hygienic Practices:AVOID CONTACT: EYES SKIN CLOTHING. DO NOT
BREATHE: DUST WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FORM:
ACIDS/ACID FUMES PROTECT FROM: HEAT MOISTURE.
Supplemental Safety and Health
THIS IS A KIT WITH PART NUMBER: 2242500, CONSISTING OF: 212699, ACID
REAGENT; 204499, CHROMIUM 2 REAGENT; 204399, CHROMIUM 1 REAGENT;
1206699, CHROMAVER 3 CHROMIUM REAGENT.THIS IS PART OF A KIT, KIT N
UMBERS, MSDS#; CLSGJ, MSDS#; CLSGK,MSDS#; CLSGL

HCC:B1
Melt/Freeze Pt:>400.C, 752.F
Spec Gravity:1.48
pH:>11
Evaporation Rate & Reference:N/A (WATER=1)
Solubility in Water:PARTIALLY SOLUBLE
Appearance and Odor:BRIGHT YELLOW POWDER, SOLID.

Stability Indicator/Materials to Avoid:YES
INCOMPATABLE WITH: ACID METALS COMBUSTIBLE MATERIALS.
Stability Condition to Avoid:STABLE WHEN STORED UNDER NORMAL
CONDITIONS. CONDITIONS TO AVOID: EXCESS MOISTURE, HEAT.
Hazardous Decomposition Products:CONTACT WITH METALS MAY RELEASE
FLAMMABLE HYDROGEN GAS. TOXIC FUMES OF: HYDROGEN BROMIDE SODIUM
MONOXIDE SULFUR OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WORK IN AN APPROVED FUME HOOD. DILUTE MATERIAL
WITH EXCESS WATER MAKING A WEAKER THAN 5% SOLUTION. ADJUST TO A PH
BETWEEN 6 AND 9 WITH AND ACID, SUCH AS SULFURIC OR CITRIC. OPEN
COLD WATER TAP COMPLET ELY, SLOWLY POUR THE REACTED MATERIAL TO THE
DRAIN. ALLOW COLD WATER TO RUN FOR 5 MINUTES TO COMPLET ELY FLUSH
THE SYSTEM.

Toxicological Information:LD50/LC50: NONE REPORTED. DERMAL TOXICITY
DATA: NONE REPORTED. MUTATION DATA: NONE REPORTED. REPRODUCTIVE
EFFECTS DATA: SODIUM SULFATE ORAL MOUSE TDLO - 14 G/KG (UNSPECIFIED
NEONATAL EFFECTS); TDLO = 60 MG/KG REPRODUCTIVE EFFECTS- EMBRYO OR
FETUS- FETOTOXICITY, SPECIFIC DEVELOPMENTAL
ABNORMAILITIES-MUSCULOSKELETAL. INGREDIENT TOXICOLOGICAL DATA:
LITHIUM HYDROXIDE ORAL RAT LD50 = 225 MG/KG; SODIUM SULFATE ORAL
MOUSE LD50 = 5989 MG/KG.

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Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:PRODUCT ECOLOGICAL DATA: NO ECOLOGICAL DATA AVAILABLE FOR
THIS PRODUCT. INGREDIENT ECOLOGICAL INFORMATION: SODIUM SULFATE
AQUATIC TOXICITY: TLM 13500 MG/L BLUEGILL SUNFISH/96 HOURS, TLM
16500 MG/L MOS QUITO FISH/96 HOURS.

Transport Information:D.O.T/I.C.A.O/I.M.O PROPER SHIPPING NAME:
CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. HAZARD CLASS 8. UN3262.
PACKAING GROUP II

SARA Title III Information:IMMEDIATE (ACUTE) HEALTH HAZARD. THIS
PRODUCT DOES NOT CONTAIN ANY CHEMICAL SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA.
Federal Regulatory Information:O.S.H.A.: THIS PRODUCT MEETS THE
CRITERIA FOR A HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZARD
COMMUNICATION STANDARD. (29 CFR 1910.1200). RCRA: CONTAINS NO RCRA
REGULATED SUBSTANCES.C.P.S.C: THE LABEL FOR THIS PRODUCT BEARS THE
SIGNAL POISON BECAUSE THE CONCENTRATION OF LITHIUM HYDROXIDE IS
GREATER THAN/EQUAL TO 10%.U.S. INVENTORY STATUS: THIS PRODUCT
CONTAINS A CHEMICAL(S) EXEMPT FROM TSCA 8(B) IN VENTORY DUE TO A
LOW VOLUME EXEMPTION HELD BY HACH COMPANY.
State Regulatory Information:CALIFORNIA PROP 65: NONE